CAS 77-58-7  Dibutyltin dilaurate  DABCO T-12  DBTDL  Niax D-22   Kosmos 19

Dibutyltin dilaurate

CAS No.77-58-7

Chemical Name:Dibutyltin dilaurate

SynonymsDBTDL;dbtl;t12;tn12;davainex;tinostat;butynorate;DIBUTYLTIN LAURATE;Dibutyltin dillaurate;DI-N-BUTYLDILAURYLTIN

CBNumber:CB7416378

Molecular Formula:C32H64O4Sn

Molecular Weight:631.56

MDL Number:MFCD00008963

Brand Designation / Product Code Table

Dibutyltin dilaurate Properties

Melting point      22-24°C

Boiling point       >204°C/12mm

Density  1.066 g/mL at 25 °C(lit.)

vapor pressure     0.2 mm Hg ( 160 °C)

refractive index   n20/D 1.471(lit.)

Flash point   >230 °F

storage temp.       Store below +30°C.

solubility       <1.43mg/l

form       Oily Liquid

Specific Gravity  1.066

color      Clear pale yellow

Water Solubility  <0.1 g/100 mL at 20 ºC

FreezingPoint      8℃

Merck    14,3038

BRN      4156980

Exposure limits    PC-TWA:0.1 mg/m3; PC-STEL:0.2 mg/m3

Stability Stability Combustible. Incompatible with strong oxidizing agents. May be air sensitive.

InChI     1S/2C12H24O2.2C4H9.Sn/c2*1-2-3-4-5-6-7-8-9-10-11-12(13)14;2*1-3-4-2;/h2*2-11H2,1H3,(H,13,14);2*1,3-4H2,2H3;/q;;;;+2/p-2

InChIKey     UKLDJPRMSDWDSL-UHFFFAOYSA-L

SMILES       CCCCCCCCCCCC(=O)O[Sn](CCCC)(CCCC)OC(=O)CCCCCCCCCCC

LogP     3.120

UNSPSC Code   12352103

NACRES     NA.22

SAFETY

Signal word        Danger

Hazard statements     H330-H301-H315-H319-H360-H370-H372-H317-H341-H410

Precautionary statements        P501-P273-P272-P270-P202-P260-P201-P271-P264-P280-P284-P302+P352-P391-P337+P313-P305+P351+P338-P308+P311-P362+P364-P333+P313-P301+P310+P330-P304+P340+P310-P403+P233-P405

target organs thymus, thymus,Immune system

PPE Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

Hazard Codes     T+,N,C,T

Risk Statements 22-26-36/38-50/53-68-48/25-43-34-61-60

Safety Statements     26-28-36/37-45-60-61-36/37/39-24-53

RIDADR     UN 2922 8/PG 3

WGK Germany 3

RTECS        WH7000000

F    10-21

Autoignition Temperature >200 °C

TSCA   TSCA listed

HazardClass       6.1

PackingGroup    III

HS Code      29319090

Storage Class      6.1C - Combustible acute toxic Cat.3

toxic compounds or compounds which causing chronic effects

Hazard Classifications       Aquatic Acute 1

Aquatic Chronic 1

Eye Irrit. 2

Muta. 2

Repr. 1B

Skin Sens. 1

STOT RE 1

STOT SE 1

Hazardous Substances Data     77-58-7(Hazardous Substances Data)

Toxicity LD50 orally in Rabbit: 175 mg/kg

REACH Registrations       Active

Limited Quantities     5.0 L (1.3 gallons) (liquid) or 5.0 kg (11 lbs) (solid)

Excepted Quantities   Max Inner Pack (30g or 30ml) and Max Outer Pack (1Kg or 1L)

Dibutyltin dilaurate Chemical Properties,Uses,Production

Organic tin additive

Dibutyltin dilaurate is an organic tin additives, and can be soluble in benzene, toluene, carbon tetrachloride, ethyl acetate, chloroform, acetone, petroleum ether and other organic solvents and all industrial plasticizers, but insoluble in water. Multipurpose high-boiling organic tin catalyst circulation of dibutyltin dilaurate are usually specially treated liquefaction, and at room temperature as a pale yellow or colorless oily liquid, when low temperature as white crystals, and it can be used for PVC additives, it also has excellent lubricity, transparency, weather resistance, and better resistance for sulfide pollution. It can also uesd the stabilizer of the soft transparent products and efficient lubricants in hard transparent products, and can also be used acrylate rubber and rubber carboxyl crosslinking reaction, the catalyst of synthesis of polyurethane foam and polyester synthetic, and RTV silicone rubber.

The above information is edited by the chemicalbook of Wang Xiaodong.

Chemical properties

It is pale yellow flammable liquid, and soluble in acetone and benzene, can not dissolve in water.

Uses

It can be used as PVC heat stabilizers, and it is the earliest used varieties in organotin stabilizers, heat resistance is less than tributyltin maleate, but it has excellent lubricity, weather resistance and transparency can be ok, and it has good compatibility with plasticizers, non-blooming, non-sulfide pollution, no adverse effects on heat sealing and printability. For it is liquid at room temperature, so the dispersion in plastic is better than solid stabilizer.The product is mainly used in soft transparent products or semi-soft products, generally in an amount of 1-2%. In hard products, the product can be used as lubricant, and when used with maleic acid organic tin or thiol-containing organic tin can improve the fluidity of the resin material. Compared with other organic tin, the goods early color large will cause yellow discoloration.The product can also be used as catalysts of synthesizing polyurethane, the curing agents of silicone rubber. In order to enhance the thermal stability, transparency, compatibility with resins, as well as improve the impact strength for hard products and its other properties, now it has developed a number of modified varieties. Lauric acid and other fatty acids is generally added in the category of pure, the epoxy ester or other metal soap stabilizer is also added in. The product is toxic materials. Rat oral is LD50 of 175mg/kg.

Production method

It is condensed by DBTO and lauric acid at 60℃. After condensation, vacuum dehydration, cooling, pressure filtration derived products.

Category

Toxic Substances.

Toxicity grading

Highly toxic.

Acute toxicity

Oral-rat LD50: 175 mg/kg; oral-mouse LDL0: 710 mg/kg.

Stimulus data

Skin-rabbit 100 mg/24 hours moderate.

Flammability hazard characteristics

Combustible fire.

Storage Characteristics

Treasury should be ventilated and low-temperature drying; and should transport separately with food materials.

Extinguishing agent

Carbon dioxide, sand, water, foam.

Occupational standards

TWA 0.1 mg (Sn)/cubic meter; STEL 0.2 mg (Sn)/cubic meter.

Chemical Properties

yellow liquid

Uses

PU catalyst, RTV silicone rubber

Uses

Stabilizer for polyvinyl chloride resins. Catalyst for curing certain silicones.

Uses

Di-n-butyltin dilaurate is used as a catalyst for the production of polyurethanes as well as for the transesterification reactions. It is involved in the vulcanization of silicones and a stabilizer in polyvinyl chloride (PVC). It acts as a rust inhibitor for polyurethanes, polyols, silicones and as a fuel additive.

Uses

Dibutyltin dilaurate has been used as a catalyst in a protocol for the covalent attachment of poly(ethylene glycol) (PEG) to silicon oxide to form a hydrophilic non-fouling surface. It can also be used as a catalyst in the preparation of polymers by reacting hydroxyl-terminated macromonomers and aliphatic diisocyanates.

General Description

Clear yellow viscous liquid.

Air & Water Reactions

Dibutyltin dilaurate may be sensitive to air or heat. . Insoluble in water.

Reactivity Profile

Dibutyltin dilaurate is strongly reactive with many other groups. Incompatible with acids and bases. Organometallics are good reducing agents and therefore incompatible with oxidizing agents.

Fire Hazard

Dibutyltin dilaurate is combustible.

Safety Profile

Poison by ingestion and intraperitoneal routes. A skin and eye irritant. Avoid the vapor produced by heating. Combustible when exposed to heat or flame; reacts with oxidizers. When heated to decomposition it emits acrid smoke and fumes. See also TIN COMPOUNDS

Toxics Screening Level

The initial threshold screening level (ITSL) for dibutyl tin dilaurate is 5 μg/m3 (8-hr averaging time).

Dibutyltin dilaurate Preparation Products And Raw materials

Raw materials

Lauric acid Dibutyltin oxide TETRABUTYLTIN

Preparation Products

methyl block RTV silicone rubber adhesive QD-200 sersies polyurethae finishes PUC series

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